2021-11-12 Pageview:845
Appearance: amber liquid
Solid content %: ≥20-25.0
Total content(by PO43-) %: ≥15.0
Density(20℃)g/cm3: ≥1.10
PH(1% aqueous solution): 2.5±1.0
Starting from the perfluoroalkyl iodoalkane, some examples of fluorocarbon surfactants are prepared.
RCH: CO, H-R, COy H
-Rp CHaCO, H-Ry CH, CH, OH–Ry CH, CHgO(CH, CH) .H
-(Ry CH.CHaO) PKO) OHRyCH: CHl-
-R.CaCHa 50, H-Rr CH, CHSH-
-RPCILCHLSCILN”(CHL) CH.CH.OH Br
–R-CHa CH, SO: NH CCH) aN”(CH) X-
–RrCH: CHASOgCH-
–Ry CH, CH, SO, NH(CH, ), N(CH, ), CH.COO
Chemical transformation of perfluoroalkyl iodoalkanes
The oligomerization method was developed by the British ICI company [44~45], with recycled ptfe powder tetrafluoroethylene anion CF, =CF, one (CF.),
Based on polymerization, prepare long carbon chain fluoroalkane tetramer:
CEGE-based intermediate is also a kind of preparation fluorine-containing
Surfactant method. Tetrafluoroethyl rocr, GA, pentamer: alkene, hexafluoropropylene and the corresponding epoxidized CBSB compound (such as hexafluoropropylene oxide) under the catalysis of fluorine KC-ion, and aprotic polar EC~CF, Anionic polymerization anti-hexamer can occur in Cu Fao solvents:
Should produce Cg~Cic perfluorooligomeric ECS KECCE products. The oligomerization product of tetrafluoroethylene is EGEFCE
Among them, pentamers account for about 65% of the entire mixture. Since the fluorine atom on the carbon atom of the double bond is easily replaced by a nucleophile, the desired linking group can be introduced through this reaction.
Leave a message
We’ll get back to you soon